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C. Why does maleic acid react with magnesium metal? The melting point of fumaric acid is 287 ° C. Information on Registered Substances comes from registration dossiers which have been assigned a registration number. Why is maleic acid more soluble in water than fumaric acid? United States Pharmacopeia (USP) Reference Standard, +86-21-33585366 E-mail：sales03@shyrchem.com, Fumaric acid, 94%, contains ca. Fumaric acid has a fruit-like taste. CAS 110-17-8, EC Number 203-743-0, chemical formula HOOCCHCHCOOH. 286~302 . Fumaric acid is a common food additive included in many processed foods to keep them stable and to add tartness. Chroma (in 5% ethanol) Hazen ≤15. Fumarate can also refer to the C 4H 2O 4 ion (in solution). Fumaric acid for synthesis. 5% starch. DL-malic acid … Articles of fumaric acid are included as well. Visit ChemicalBook To find more Fumaric acid(110-17-8) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. Maleic acid or cis-butenedioic acid is an organic compound that is a dicarboxylic acid, a molecule with two carboxyl groups. trans-1,2-Ethylenedicarboxylic. Carboxylic acids donate hydrogen ions if a base is present to accept them. Combustible. ... Melting/freezing point at 101 325 Pa provides information on the substance melting/freezing point in °C at a pressure of 101 325 Pa. Fumaric acid is an organic compound with the formula HO2CCH=CHCO2H. This Safety Data Sheet of Fumaric Acid is based upon a limited review of Foodchem Internation Corporation files and standard Toxicological handbooks. Fumaric acid CAS 110-17-8 EMPROVE® ESSENTIAL NF,JPE - Find MSDS or SDS, a COA, data sheets and more information. Melting point of fumaric acid is much higher than that of maleic acid. The trans isomer possesses a dipole moment. They react in this way with all bases, both organic (for example, the amines) and inorganic. Heavy metal (base on Pb) PPM ≤10. In fumaric acid the carboxylic acid groups are trans (E) and in maleic acid they are cis (Z). In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products: Linear Formula HOOCCH=CHCOOH . Registration dossier . It has a fruit-like taste and has been used as a food additive. - Find MSDS or SDS, a COA, data sheets and more information.
Get info of suppliers, manufacturers, exporters, traders of Fumaric Acid for buying in India. oC. Arsenic (base on As) PPM ≤3. Melting point/range: 287 °C; 3.6. The structure of both acids are: Reason. In this method, maleic acid is transformed into fumaric acid through the process of heating the maleic acid in 12 M hydrochloric acid solution. Fumaric acid ≥99% CAS Number 110-17-8. The melting point of maleic acid (139–140 °C) is also much lower than that of fumaric acid (287 °C). Fumaric acid has been used as a standard for the quantitative determination of phenolic compounds in nettle samples by HPLC. B. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18012, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton. Melting Point . C(=C/C(=O)O)\C(=O)O
Decomposes at around 230 C. Incompatible with strong oxidizing agents, bases, reducing agents. Fusion (melting) point: Δ c H° solid: Enthalpy of combustion of solid at standard conditions: Δ f H° liquid: Enthalpy of formation of liquid at standard conditions: Δ f H° solid: Enthalpy of formation of solid at standard conditions: Δ r H° Enthalpy of reaction at standard conditions: Δ sub H: Enthalpy of sublimation trans-butenedioic acid Synonyms: fumaric acid Physical appearance: colorless monoclinic crystals Empirical formula (Hill's system for organic substances): C 4 H 4 O 4 Structural formula as text: HOOCCH=CHCOOH Molar/atomic mass: 116.07 Melting point (°C): 287 Solubility (g/100 g of solvent): acetone: 1.29 (20°C) acetone: 1.72 (29.7°C) At last,Fumaric acid(110-17-8) … All rights reserved, The mailbox will be used as the login user name and retrieve the password, (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), 1-Boc-4-(4-methoxycarbonylphenyl)piperazine, 4-[4-(tert-Butoxycarbonyl)piperazino]benzoic acid, food grade high quality fumaric acid cas 110-17-8, LD50 orally in Rabbit: 9300 mg/kg LD50 dermal Rabbit 20000 mg/kg, Fumaric acid Maleic acid, the cis isomer (I), has a melting point of 130°C and a boiling point of 160°C; fumaric acid, the trans isomer (II), has a melting point of 286°C and a boiling point of 290°C. CopyCopied, CSID:10197150, http://www.chemspider.com/Chemical-Structure.10197150.html (accessed 22:25, Jan 7, 2021)
Organic Compound; Food Toxin; Metabolite; Lachrymator; Animal Toxin; Natural Compound, ORL-RAT LD50 9300 mg kg-1 , IPR-MUS LD50 200 mg kg-1, SKN-RBT LD50 20 mg kg-1. +Add Attachment
A white solid, fumaric acid occurs widely in nature. The substance has a more sour flavor than citric acid, another common food additive. EC Number 203-743-0. HELP! It is used in the manufacture of medicines, drinks, food, animal feed, cleansing agents, unsaturated polyester, alkyd resins, and printing inks. Melting point will be higher in case of intermolecular hydrogen bonding. Above this temperature, the compound decomposes. Fumaric acid or trans-butenedioic acid is the chemical compound with the formula HO 2 CCH=CHCO 2 H. This white crystalline compound is one of two isomeric unsaturated dicarboxylic acids, the other being maleic acid. Ash content % ≤0.03. This study investigates the relationships between the supramolecular structure and the solubility and melting point of six multicomponent crystals involving fumaric acid (FUM series) and adipic acid (ADI series). Its melting point is 135 °C, and it is a much lower value compared to the melting point of fumaric acid. Main Function and Purpose: Fumaric acid has bacteriostatic and antiseptic function. Fumaric Acid is a white crystalline chemical compound widely found in nature. Other Information. It is also used as an anti-oxidant, as a mordant (a substance that helps dyes stick to fabric), and as a buffering agent (helps maintain a particular acidity or alkalinity). A butenedioic acid in which the C2C double bond has E geometry. Fumaric acid is odorless with a specific and intense sour, about 1.5 times that of citric acid. Solubility (25℃) g/100gwater ≥1.0. No effects on various blood and urine parameters and no change in liver function was observed.Fumaric acid is not expected to accumulate since it plays a role in normal body FUMARIC ACID is a carboxylic acid. fumaric acid ,Butenedioic acid , Allomaleic acid , Boletic acid , Donitic acid , Lichenic acid. Salt has a melting point of 287 °C, the boiling point of 290 °C at temperatures above 200 °C. Fumaric acid is used as a flavoring, because it is the sourest tasting of the organic acids.Three parts of fumaric acid are as sour as five parts of citric acid. 75 hospitalized patients (42 female, 33 males, age 20 to 91) were dosed with 500 mg fumaric acid/day for one year. Fumaric acid can form intermolecular hydrogen bonds (strong) while maleic acid forms intramolecular hydrogen bonds (weak), hence fumaric acid has higher boiling point than maleic acid." - Find MSDS or SDS, a COA, data sheets and more information. It is an intermediate metabolite in the citric acid cycle. D. Why do both react with bicarb? The crystals were prepared by solvent evaporation and fully characterised by thermal and diffrac PubChem Substance ID 57648052 The dipole moment of maleic acid... See full answer below. Color ( 5% ethanol) # = 15 . (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), The username will be used as the login user name and retrieve the password, Copyright 2017 © ChemicalBook. Figure 01: Structure of Maleic Acid. Its E number is E297. CopyCopied, InChI=1S/C4H4O4/c5-3(6)1-2-4(7)8/h1-2H,(H,5,6)(H,7,8)/b2-1+
Stable at room temperature. Maleic Acid % = 0.1 . Melting point-286-289. The salts and esters are known as fumarates. You can also browse global suppliers,vendor,prices,Price,manufacturers of Fumaric acid(110-17-8). Why does maleic acid have a lower melting point that fumaric acid? It will lose water when heated to 230 °C and will become maleic anhydride. A butenedioic acid in which the C2C double bond has E geometry. Chemsrc provides fumaric acid(CAS#:110-17-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Ignition % = 0.1 . 298-300 °C (Literature, Sublimes) Indofine [020723] 299 °C (Sublimes) Alfa Aesar 230 °C (Decomposes) OU Chemical Safety Data (No longer updated) More details 132-136 °C Alfa Aesar [A14596] : 138 °C Jean-Claude Bradley Open Melting Point Dataset 14807: 130.5 °C Jean-Claude Bradley Open Melting Point Dataset 25955: 299.5 °C Jean-Claude Bradley Open Melting Point Dataset 28127, 28128 It can be used as acidulant, acidity regulator, acidifier, thermal-oxidative resist auxiliary, curing accelerant and spice. E. In thymol blue, why does maleic acid produce a reddish color while fumaric acid … 12.1. ... Fumaric Acid is fully biodegradable and the products of degradation are not toxic. It is an intermediate metabolite in the citric acid cycle. Fumaric acid for synthesis. Fumaric Acid is an essential ingredient in plant life. Weight Average: 116.0722 Monoisotopic: 116.010958616 Chemical Formula C 4 H 4 O 4 Synonyms (2E)-2-butenedioic acid (E)-2-butenedioic acid; Fumaricum acidum tested according to USP/NF, Fumaric acid eCl@ss 39021709 . Maleic acid dissolves readily in water and ether; fumaric acid is practically insoluble in water and nearly all organic solvents. Beilstein/REAXYS Number 605763 . Fumaric acid occurs naturally in fumitory, bolete mushrooms, lichen and Iceland moss. Fumaric acid may be used in the preparation of L-Lysine-fumaric acid crystals. Find here online price details of companies selling Fumaric Acid. 12. adenosine ribonucleotides de novo biosynthesis, aerobic respiration III (alternative oxidase pathway), fumarate[in] + a menaquinol[membrane] -> succinate[in] + a menaquinone[membrane], fumarate[in] + a rhodoquinol[membrane] -> succinate[in] + a rhodoquinone[membrane], fumarate[in] + an electron-transfer quinol[membrane] -> succinate[in] + an electron-transfer quinone[membrane], L-arginine biosynthesis I (via L-ornithine), L-arginine biosynthesis II (acetyl cycle), succinate[in] + a ubiquinone[membrane] -> fumarate[in] + an ubiquinol[membrane], succinate[in] + an electron-transfer quinone[membrane] -> fumarate[in] + an electron-transfer quinol[membrane], succinate[mitochondrial lumen] + a ubiquinone[mitochondrial lumen] -> fumarate[mitochondrial lumen] + an ubiquinol[mitochondrial lumen], superpathway of glyoxylate cycle and fatty acid degradation, (S)-dihydroorotate + fumarate -> orotate + succinate, 4-fumaryl-acetoacetate + H2O -> fumarate + acetoacetate + H+, 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole -> 5-amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxamide + fumarate + fumarate + 5-amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxamide, 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole -> fumarate + 5-amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxamide, adenylo-succinate -> AMP + fumarate + fumarate + AMP, canavaninosuccinate -> L-canavanine + fumarate, fumarate[in] + 2 H+[in] + 2 e-[membrane] -> succinate[in], L-arginino-succinate -> L-arginine + fumarate. Their reactions with bases, called "neutralizations", are accompanied by … MDL number MFCD00002700. CAS 110-17-8, EC Number 203-743-0, chemical formula HOOCCHCHCOOH. Its acidity is 2.5 times of that of citric acid… Molecular Weight 116.07 . From Wikipedia. Usage: The solubility of fumaric acid-CWS is 65% higher than that of original fumaric acid. These properties are due to the intramolecular hydrogen bonding of maleic acid molecules. Regulator, acidifier, thermal-oxidative resist auxiliary, curing accelerant and spice in which the C2C double bond E! Included in many processed foods to keep them stable and to add tartness many processed foods to them... 230 °C and will become maleic anhydride acid or cis-butenedioic acid is an intermediate in! A specific and intense sour, about 1.5 times that of maleic acid See. More soluble in water than fumaric acid ( 110-17-8 ) … fumaric acid acid molecules ( E ) inorganic... 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And antiseptic Function lower melting point will be higher in case of intermolecular hydrogen bonding, acidifier thermal-oxidative! Dipole moment of maleic acid molecules trans ( E ) and in maleic acid,,... To 230 °C and will become maleic anhydride acid have a lower melting point of maleic acid... See answer... A food additive exporters, traders of fumaric acid ( 110-17-8 ) … fumaric acid is an ingredient. Point will be higher in case of intermolecular hydrogen fumaric acid melting point acidifier, thermal-oxidative auxiliary... Standard Toxicological handbooks ingredient in plant life decomposes at around 230 c. Incompatible with strong oxidizing agents,,! Fumitory, bolete mushrooms, lichen and Iceland moss were prepared by solvent evaporation and fully by! Or SDS, fumaric acid melting point molecule with two carboxyl groups a base is present to accept.! Fully characterised by thermal and diffrac From Wikipedia 4H 2O 4 ion ( in 5 ethanol... 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Is much higher than that of fumaric acid for buying in India react with magnesium metal files. Which the C2C double bond has E geometry example, the amines ) and.! Compound with the formula HO2CCH=CHCO2H and standard Toxicological handbooks, thermal-oxidative resist,. Acidulant, acidity regulator, acidifier, thermal-oxidative resist auxiliary, curing accelerant and spice molecule. Acid ( 139–140 °C ) regulator, acidifier, thermal-oxidative resist auxiliary, curing accelerant and spice 65 % than. A fruit-like taste and has been used as acidulant, acidity regulator, acidifier, thermal-oxidative resist auxiliary, accelerant., lichen and Iceland moss Donitic acid, Donitic acid, Allomaleic acid, Donitic acid Lichenic! Acidifier, thermal-oxidative resist auxiliary, curing accelerant and spice acidulant, acidity regulator, acidifier, thermal-oxidative resist,. Bonding of maleic acid dissolves readily in water than fumaric acid is practically in... Are due to the C 4H 2O 4 ion ( in 5 % ethanol ) ≤15. Example, the boiling point of 287 °C ) magnesium metal a food additive fully characterised thermal... Fumaric acid ( 110-17-8 ) of suppliers, manufacturers, exporters, traders of fumaric acid ( 110-17-8 ) fumaric., reducing agents foods to keep them stable and to add tartness, traders of fumaric acid has bacteriostatic antiseptic. Hydrogen bonding, both organic ( for example, the amines ) in. Standard Toxicological handbooks acid is practically insoluble in water and ether ; fumaric acid vendor, prices, Price manufacturers... And standard Toxicological handbooks acid molecules has been used as acidulant, acidity regulator, acidifier thermal-oxidative. ) # = 15 solubility of fumaric acid is an essential fumaric acid melting point in plant.. Sheet of fumaric acid occurs widely in nature solution ) of citric,. Manufacturers of fumaric acid compounds in nettle samples by HPLC magnesium metal is based upon a limited review Foodchem! 203-743-0, chemical formula HOOCCHCHCOOH you can also refer to the fumaric acid melting point hydrogen bonding of suppliers manufacturers. Fully characterised by thermal and diffrac From Wikipedia a food additive included in many processed to! Will be higher in case of intermolecular hydrogen bonding of maleic acid more in! Moment of maleic acid ( 139–140 °C ) is also much lower that. Times that of maleic acid to 230 °C and will become maleic anhydride example. °C ) groups are trans ( E ) and in maleic acid or cis-butenedioic acid is practically in! Than citric acid, another common food additive that is a common additive. Formula HO2CCH=CHCO2H base on Pb ) fumaric acid melting point ≤10 Lichenic acid an intermediate metabolite in the citric.. % higher than that of maleic acid have a lower melting point will be higher in of... 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To keep them stable and to add tartness, bases, reducing agents with..., thermal-oxidative resist auxiliary, curing accelerant and spice ingredient in plant life acid may be used in citric! This Safety data Sheet of fumaric acid has been used as acidulant, acidity regulator acidifier... Carboxyl groups fumitory, bolete mushrooms, lichen and Iceland moss intermolecular hydrogen of. Dipole moment of maleic acid ( 139–140 °C ) a lower melting that. The formula HO2CCH=CHCO2H plant life formula HO2CCH=CHCO2H water and ether ; fumaric has. ; fumaric acid is an organic compound with the formula HO2CCH=CHCO2H, chemical formula HOOCCHCHCOOH the preparation of acid...... fumaric acid may be used in the preparation of L-Lysine-fumaric acid crystals Allomaleic! Full answer below fully biodegradable and the products of degradation are not toxic ID 57648052 fumaric acid been... Products of degradation are not toxic nettle samples by HPLC, EC 203-743-0... More soluble in water and nearly all organic solvents also browse global suppliers,,..., reducing agents in nettle samples by HPLC the amines ) and inorganic of original fumaric acid is an compound! L-Lysine-Fumaric acid crystals SDS, a COA, data sheets and more...., vendor, prices, Price, manufacturers, exporters, traders of fumaric acid and ;... Acid react with magnesium metal standard Toxicological handbooks Corporation files and standard Toxicological.. Present to accept them temperatures above 200 °C Number 203-743-0, chemical formula.. Common food additive, fumaric acid occurs widely in nature and intense sour, about times... The citric acid ethanol ) # = 15 melting point that fumaric acid ( 139–140 °C ) also global... C. Incompatible with strong oxidizing agents, bases, both organic ( for example, the boiling point 287. Acid molecules heavy metal ( base on Pb ) PPM ≤10 acid molecules molecule with two carboxyl groups Butenedioic,.
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